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Molecular Rearrangements. III. The Mechanism of the Wagner-Meerwein Rearrangement in the 1,2,2-Triphenylethyl System 1

✍ Scribed by Collins, Clair J.; Bonner, William A.

Book ID
127085364
Publisher
American Chemical Society
Year
1955
Tongue
English
Weight
1015 KB
Volume
77
Category
Article
ISSN
0002-7863

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## Abstract On treatment with HSO~3~F in SO~2~C1F at 0Β°, 3‐hydroxy‐2,2‐dimethyl‐3‐phenyl‐propionic acid (**1a**) is transformed into 2‐phenyl‐3‐methyl‐2‐butenoic acid (**2a**) (isolated yield: 40–44%). Using monolabelled [3‐^13^C]‐**1a** (**1a**\*) and doubly labelled [1,3‐^13^C~2~]‐**1a** (**1a**\