✦ LIBER ✦
Molecular quadrupole moment determinations from measurements of laser wave hyper-Rayleigh scattering by dense fluids
✍ Scribed by J.R. Lalanne; F.B. Martin; S. Kielich
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 412 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Hyper-Rayleigh scattering (second-harmonic scattering, SHS) of laser waves by dense tluids composed ofcentrcsymmetric molecules permits the measurement of the mean-squared value of the internal molecukr electric field !Fi>. In the case of quadrupolar molecules, these measured values can be used to determine the quedrupolc mamcnt of the scattering molecules. NumcricaJ results are given for cyclohexane and fmnsdecahydronaphthdene amounting to 11 and 9.8, respectiveIy, in 10Wz6 esu.