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Molecular-Programmed Self-Assembly of Homo- and Heterometallic Penta- and Hexanuclear Coordination Compounds: Synthesis, Crystal Structures, and Magnetic Properties of Ladder-Type Cu II2 M II x (M = Cu, Ni; x = 3, 4) Oxamato Complexes with Cu II2 Metallacyclophane Cores

✍ Scribed by Pardo, Emilio; Ruiz-García, Rafael; Lloret, Francesc; Julve, Miguel; Cano, Joan; Pasán, Jorge; Ruiz-Pérez, Catalina; Filali, Yasmine; Chamoreau, Lise-Marie; Journaux, Yves


Book ID
127084516
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
336 KB
Volume
46
Category
Article
ISSN
0020-1669

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New homo-and heterometallic hexanuclear complexes of formula {[Cu(tmen) tetrakis(aminomethylene)methanetetrakis(oxamic acid), tmen = N,N,NЈ,NЈ-tetramethylethylenediamine, pmdien = N,N,N',N',N''-pentamethyldiethylenetriamine, and cyclam = 1,4,8,11-tetraazacyclotetradecane] have been synthesized. The