Molecular oxygen as a paramagnetic NMR probe of protein solvent exposure and topology
โ Scribed by Irina Bezsonova; Julie Forman-Kay; R. Scott Prosser
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 700 KB
- Volume
- 32A
- Category
- Article
- ISSN
- 1546-6086
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
## Abstract The nitrogen NMR shielding of __tert__โbutyl isocyanide (1) is shown to be a sensitive probe of solvent polarizabilityโpolarity, since the shielding is demonstrated to be unresponsive to hydrogen bonding effects between 1 and the solvent. The direction of solvent effects observed is exp
## Abstract Substitution of Yb^3+^ for the Ca^2+^ in bovine ฮฑโlactalbumin affords a derivative that gives rise to several isotropically shifted ^1^H NMR signals in the range 80 to โ 35 ppm in D~2~O. Despite the broadness of the isotropically shifted features, cross signals in both NOESY and COSY sp