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Molecular orbital study of resonance electron capture by 3-substituted aliphatic acids and their methyl esters

✍ Scribed by Valeriy G. Voinov; Nikolay E. Petrachenko; Vladimir E. Dorofeyev; Hirohide Nakamatsu; Takeshi Mukoyama

Book ID: 107920636
Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 866 KB
Volume: 137
Category: Article
ISSN: 0168-1176
DOI: 10.1016/0168-1176(94)04028-1

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## Abstract During UV.‐irradiation of aliphatic carboxylic acids and esters in aqueous and nonaqueous solutions various alkyl and acyl type radicals derived from parent compounds and solvents have been observed by ESR.‐spectroscopy. The structures of the radicals point to α‐cleavage, β‐dehalogenati