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Molecular orbital study of hyperfine splitting constants in ethyl and cyclohexadienyl radicals

โœ Scribed by Pierluigi Nordio; Maria V. Pavan; Giovanni Giacometti


Publisher
Springer
Year
1963
Tongue
English
Weight
339 KB
Volume
1
Category
Article
ISSN
1432-2234

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Local density effects on the hyperfine s
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The density dependences of the nitrogen hyperfine coupling constant (a N ) and line width (DH pp ) of the 2,2,6,6tetramethylpiperidine-1-oxyl (TEMPO) free radical have been investigated at near-infinite dilution in gaseous and supercritical carbon dioxide using steady-state EPR spectroscopy. The loc