The structure and energy of SiH+5. compa
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Paul von RaguΓ© Schleyer; Yitzhak Apeloig; Dorit Arad; Brian T. Luke; John A. Pop
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Article
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1983
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Elsevier Science
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English
β 517 KB
Diiicrences between SiHS and CH; are more significant than the similarities. The proton affinity of Sib exceeds that of CH4 by ~25 kcal/mol. but the heat of hydrogenation of SiH; is smaller than that of CH: by nearly the mrne amount. Like CH:, the Cs structures of SiH: are preferred, but SiH: is bes