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Molecular Orbital and IMOMM Studies of the Chain Transfer Mechanisms of the Diimine−M(II)-Catalyzed (M = Ni, Pd) Ethylene Polymerization Reaction

✍ Scribed by Musaev, Djamaladdin G.; Froese, Robert D. J.; Morokuma, Keiji


Book ID
121339013
Publisher
American Chemical Society
Year
1998
Tongue
English
Weight
200 KB
Volume
17
Category
Article
ISSN
0276-7333

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The 6exibility of the MPS ؊ 4 chains of KMPS 4 (M ‫؍‬ Ni, Pd) was examined by performing contact mode atomic force microscopy (AFM) measurements for the (001) surface of KNiPS 4 and also by performing extended HuK ckel tight binding calculations for the [M(PS 4 ) 2 ] 4؊ entities of KMPS 4 . The obse