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Molecular orbital analysis of mono- and di-carbido-gold cluster compounds

✍ Scribed by D.Michael P. Mingos; René P.F. Kanters

Publisher
Elsevier Science
Year
1990
Tongue
English
Weight
803 KB
Volume
384
Category
Article
ISSN
0022-328X

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The reaction chemistry of [Pd(AuPPh&](NO 3 ) 2 with the halide ions Cl-, Br-and I-and with the pseudohalide CN-has been studied. Acetone solutions of [Pd(AuPPh,),](NO,), reacted with these ions to give the new Pd-Au clusters (I)Pd(AuPPh&(AuI)2, [Pd(AuPPh,),(AuBr),]+, Pd(AuPPh,),(AuCl), and Pd(AuPPh&