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Molecular motions in solid saccharides studied by NMR spectroscopy

✍ Scribed by E.C. Reynhardt; L. Latanowicz


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
450 KB
Volume
251
Category
Article
ISSN
0009-2614

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✦ Synopsis


Analyses of spin-lattice relaxation time and second moment measurements of the polycrystalline saccharides methyl a-D-mannopyranoside, methyl fl-D-arabinopyranoside, methyl fl-L-arabinopyranoside and fl-D-allose have revealed, apart from methyl group reorientations in the methyl pyranosides, the jump motion of a hydroxyl proton in a hydrogen bond in fl-D-allose and trans-gauche reodentations of CH2OH groups in methyl a-D-mannopyranoside and fl-D-allose.


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