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Molecular motion in the supercooled liquid state: Small molecules in slow motion

✍ Scribed by G. Williams; P.J. Hains

Publisher
Elsevier Science
Year
1971
Tongue
English
Weight
495 KB
Volume
10
Category
Article
ISSN
0009-2614

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✦ Synopsis

It is shown that the motion of smali molecules in the supercooted Eqiquid st2te may occur at reorientation rates 1Oa to IO" set slower than. in normal low viscosity solvents. The detailed dielectric bebzviaur of anthrone and nitrobenzone in supercooled ortho-terphenyl is de&xl%%& and interpreted as a moperative process. The important implications of this work in relation to the behationr of solid polymers is briefly discussed.

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