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Molecular models of the structure of concentrated electrolytic solutions

✍ Scribed by M.Alves Marques; M.I. Cabaço


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
1017 KB
Volume
123
Category
Article
ISSN
0009-2614

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✦ Synopsis


An approximate

method is suggested to calculate, from s = (4q//X)sinf) = 1 A-' up to high values of s, the X-ray intensity scattered by concentrated electrolytic solutions of cations and anions with different valencies. Several (six) molecular models were idealized to obtain, in this large interval of s, an intensity approaching the X-ray intensity scattered by 3.96 M aqueous solution of indium nitrate; it is demonstrated that a liquid-type quasi-close-packing of indium complexes is the more adequate model.


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