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Molecular modeling of the mechanisms of thermolysis of nitramino-1,2,4-triazoles

✍ Scribed by V. L. Korolev; T. V. Petukhova; E. A. Bakhmatova; T. S. Pivina; A. B. Sheremetev


Book ID
118298098
Publisher
Springer US
Year
2006
Tongue
English
Weight
348 KB
Volume
42
Category
Article
ISSN
0009-3122

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Thermolysis of N-allylic 1,2,4-triazoles
✍ Per H. J. Carlsen; KΓ₯re B. JΓΈrgensen πŸ“‚ Article πŸ“… 1997 πŸ› Journal of Heterocyclic Chemistry 🌐 English βš– 778 KB

## Abstract A number of 4‐allylic substituted 3,5‐diphenyl‐4__H__‐1,2,4‐triazoles were thermolyzed at 315–320Β° in evacuated glass ampoules. The main reaction in the melt was rearrangement to the corresponding 1‐substituted triazoles, which appeared to proceed __via__ competing S~N~2 and S~N~2β€² mech