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Molecular Mobility of Peroxy Radicals at the Ends of Nonisolated Polystyrene Chains Tethered on the Solid Surface of Poly(tetrafluoroethylene) in a Vacuum

✍ Scribed by Sakaguchi, Masato; Iwamura, Takeru; Yamamoto, Katsuhiro; Miwa, Yohei; Shimada, Shigetaka; Sakai, Masahiro

Book ID: 126121423
Publisher: American Chemical Society
Year: 2008
Tongue: English
Weight: 122 KB
Volume: 41
Category: Article
ISSN: 0024-9297
DOI: 10.1021/ma701925v

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Poly(isobutylene) (PIB) chains with a radical at the chain end were graftcopolymerized on the poly(tetrafluoroethylene) (PTFE) surface in vacuo at 77 K. The PIB chains tethered on the PTFE surface in vacuo were regarded as isolated chains from neighboring tethered PIB chains. The molecular motion of

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