Molecular mechanism of plastic deformation of polyethylene
β Scribed by Peterlin, A.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 2007
- Weight
- 884 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0449-2994
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Morphological and mechanical changes during drawing of polyethylene of low density (highly branched Lupolen of relatively high molecular weight and linear ACX of extremely high molecular weight) were studied by small angle X-ray scattering, observation of true stress-strain curves, crystallinity det
Young's modulus E for polyethylene in the chain direction is calculated with molecular orbital theory applied to n-alkanes C3Hs through n-Cl3HZ8 and analyzed with the clusterdifference method. Semiempirical CNDO, MNDO, and AM1 models and ab initio HF/ STO-3G, HF/6-31G, HF/6-31G\*, and MP2/6-31G\* mo