✦ LIBER ✦

Molecular Mechanism for H 2 Release from BH 3 NH 3 , Including the Catalytic Role of the Lewis Acid BH 3

✍ Scribed by Nguyen, Minh Tho; Nguyen, Vinh Son; Matus, Myrna H.; Gopakumar, G.; Dixon, David A.

Book ID: 120600363
Publisher: American Chemical Society
Year: 2007
Tongue: English
Weight: 557 KB
Volume: 111
Category: Article
ISSN: 1089-5639
DOI: 10.1021/jp066175y

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Theoretical study of the hydrogen releas

Theoretical study of the hydrogen release mechanism from a lithium derivative of ammonia borane, LiNH2BH3–NH3BH3

✍ Saartje Swinnen; Vinh Son Nguyen; Minh Tho Nguyen 📂 Article 📅 2011 🏛 Elsevier Science 🌐 English ⚖ 994 KB

Computational Study of the Release of H

Computational Study of the Release of H 2 from Ammonia Borane Dimer (BH 3 NH 3 ) 2 and Its Ion Pair Isomers

✍ Nguyen, Vinh Son; Matus, Myrna H.; Grant, Daniel J.; Nguyen, Minh Tho; Dixon, Da 📂 Article 📅 2007 🏛 American Chemical Society 🌐 English ⚖ 849 KB

Computational Study of the Release of H2

Computational Study of the Release of H2 from Ammonia Borane Dimer (BH3NH3)2 and Its Ion Pair Isomers.

✍ Vinh Son Nguyen; Myrna H. Matus; Daniel J. Grant; Minh Tho Nguyen; David A. Dixo 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 11 KB 👁 1 views

Systematic kinetic study of H2release fr

Systematic kinetic study of H2release from the dimer of lithium amidoborane (LiNH2BH3)2

✍ Kun Wang, Jian-Guo Zhang, Wei Yang, Man Wu, Tian-Tian Man… 📂 Article 📅 2012 🏛 Springer 🌐 English ⚖ 851 KB

New Insights into Factors Influencing BN

New Insights into Factors Influencing BN Bonding in X:BH3−nFn and X:BH3−nCln for X=N2, HCN, LiCN, H2CNH, NF3, NH3 and n=0–3: The Importance of Deformation

✍ Prof. Ibon Alkorta; Prof. José Elguero; Prof. Janet E. Del Bene; Prof. Otilia Mó 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 487 KB 👁 2 views

An alternative mechanism of BH2SH format

An alternative mechanism of BH2SH formation in the reaction of B2H6 with SH2: concerted elimination of BH3 and H2 from H2S ·B2H6. Ab initio MO study

✍ Alexander M. Mebel; Djamaladdin G. Musaev; Keiji Morokuma 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 411 KB

An alternative mechanism of mercaptoborane, BH,SH, formation is proposed for the reaction of BzHs with SH2. It involves concerted elimination of BH3 and H2 from the H2SB2Hs complex and the highest energy on the pathway relative to SH, + B2H6 is 27.4 kcal/mol at MP4(SDTQ)/6-31 +G(2d, p)//MP2(FULL)/6\