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Molecular Mechanics Study of the Complexes of β-Cyclodextrin with 4-(dimethylamino)benzonitrile and Benzonitrile

✍ Scribed by Javier Pozuelo; Asao Nakamura; Francisco Mendicuti

Book ID
110257531
Publisher
Springer Netherlands
Year
1999
Tongue
English
Weight
390 KB
Volume
35
Category
Article
ISSN
0923-0750

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The structure of 4-(N,N-dimethylamino)be
The structure of 4-(N,N-dimethylamino)benzonitrile and its van der Waals complexes
✍ O. Kajimoto; H. Yokoyama; Y. Ooshima; Y. Endo 📂 Article 📅 1991 🏛 Elsevier Science 🌐 English ⚖ 398 KB

The structure of N,N-dimethylaminobenzonitrile (DMABN) was determined using microwave and high-resolution laser spectroscopy. In the ground state, the molecule is found to be nearly planar with the inversion angle being about 15". In the excited state, however, the dimethylamino group rotates by 30"