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Molecular-mechanics calculations for H2C(CX3)2, X2C(CX3)2, H2Si(CX3)2 and X2Si(CX3)2 molecules with X=F, Cl and Br

✍ Scribed by Reidar Stølevik; Pirkko Bakken

Book ID
103207922
Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
430 KB
Volume
145
Category
Article
ISSN
0022-2860

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Products, rate constants and mechanisms
Products, rate constants and mechanisms of gas-phase reactions of CX3+, CX2+, CX+ (X = F and/or Cl) and Cl+ with 1,1,1- and 1,1,2-trichlorotrifluoroethane
✍ Ester Marotta; Cristina Paradisi 📂 Article 📅 2001 🏛 John Wiley and Sons 🌐 English ⚖ 159 KB

## Abstract The gas‐phase ion chemistry of 1,1,1‐ and 1,1,2‐trichlorotrifluoroethane was investigated with an ion trap mass spectrometer. Following electron ionization both compounds (M) fragment to [M − Cl]^+^, CX~3~^+^, CX~2~^+^, CX^+^ (X = F and/or Cl) and Cl^+^. The reactivity of each of these