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Molecular iodine: a green and inclusive catalyst for the synthesis of highly functionalized 1,3,5-trisubstituted pyrazoles in aqueous medium

โœ Scribed by Rai, Pratibha ;Srivastava, Madhulika ;Singh, Jaya ;Singh, Jagdamba


Book ID
121462425
Publisher
The Royal Society of Chemistry
Year
2014
Tongue
English
Weight
405 KB
Volume
4
Category
Article
ISSN
2046-2069

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Molecular iodine in [bmim][BF4]: a highl
โœ Manika Dewan; Ajeet Kumar; Amit Saxena; Arnab De; Subho Mozumdar ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 456 KB

Aldehydes and mercaptoacetic acid are coupled in the presence of a catalytic amount of economical and non-toxic molecular iodine in [bmim][BF 4 ] ionic liquid under mild conditions to afford the corresponding 1,3-oxathiolan-5-one in excellent yields. Molecular iodine acts faster in ionic liquids whe