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Molecular Geometry of Monomeric and Dimeric Yttrium Trichloride from Gas-Phase Electron Diffraction and Quantum Chemical Calculations

✍ Scribed by Réffy, Balázs; Marsden, Colin J.; Hargittai, Magdolna


Book ID
126262577
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
94 KB
Volume
107
Category
Article
ISSN
1089-5639

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Molecular geometry of monomeric and dime
✍ Magdolna Hargittai; Mária Kolonits; Lajos Godorhazy 📂 Article 📅 1996 🏛 Elsevier Science 🌐 English ⚖ 413 KB

Aluminum tribromide is present in the vapor phase in an equilibrium of monomeric and dimeric forms, with increasing amount of monomers as the temperature of the vapor increases. The molecular geometry of both forms has been determined by high-temperature electron diffraction, the monomer at 830 K an