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Molecular dynamics simulation of diffusion of small molecules in polymers. II. Effect of free volume distribution

✍ Scribed by Takeuchi, Hisao; Roe, Ryong-Joon; Mark, James E.

Book ID
120428843
Publisher
American Institute of Physics
Year
1990
Tongue
English
Weight
849 KB
Volume
93
Category
Article
ISSN
0021-9606

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## Abstract In the framework of the free‐volume (FV) theory, a new equation was derived for the evaluation of self‐diffusion coefficients of small molecules in polymers above the mixture glass transition temperature. The derivation of the equation turned out to be straightforward once the equivalen