Molecular dynamics of the Cl3PNC(CH3)3crystal from1H NMR and35Cl NQR data
β Scribed by G. E. Kibrik; I. A. Kyuntsel'; V. A. Mokeeva; Yu. I. Rozenberg; G. B. Soifer
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1979
- Tongue
- English
- Weight
- 280 KB
- Volume
- 19
- Category
- Article
- ISSN
- 0022-4766
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The reorientation of CClF, groups in N(CH,),H(ClF,CCOO), has been studied using pulsed NQR and NMR techniques. The temperature dependence of both chlorine ("'Cl) NQR and fluorine ('"F) NMR spin-lattice relaxation has been measured T,, of chlorine is attributed to the sum of two contributions: the re
A 35Cl NQR study of 2-chloro-3-pyridinol showed the presence of four NQR signals at 77 K. One of the lines showed a positive temperature coefficient of the NQR frequency. 'HNMR studies showed the presence of intramolecular hydrogen bonding, and the anomalous NQR temperature dependence has been expla