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Molecular complexes for efficient metathesis of olefins. The oxo-ligand as a catalyst?cocatalyst bridge and the nature of the active species

✍ Scribed by Kress, Jacky; Wesolek, Marcel; Le Ny, Jean-Pierre; Osborn, John A.


Book ID
118032426
Publisher
The Royal Society of Chemistry
Year
1981
Tongue
English
Weight
182 KB
Volume
0
Category
Article
ISSN
0022-4936

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Zirconium complexes as catalysts for the
✍ David Jones; Kingsley Cavell; Wilhelm Keim πŸ“‚ Article πŸ“… 1999 πŸ› Elsevier Science 🌐 English βš– 309 KB

Highly effective catalysts for the conversion of ethylene into linear a-olefins may be generated in situ from zirconium tetrachloride, a b-aminoketone or b-aminothioketone ligand and an alkylaluminium chloride Lewis acid cocatalyst. Ε½ . Catalysts may also be generated from ZrCl P 2HL adducts where