Molecular brushes with extreme grafted side chain densities
β Scribed by Jae Min Bak; Gourishanker Jha; Eungjin Ahn; Seo-Hyun Jung; Han Mo Jeong; Byeong-Su Kim; Hyung-il Lee
- Book ID
- 116843602
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 477 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0032-3861
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## Abstract We report molecular dynamics simulations on bottleβbrush polyelectrolytes endβgrafted to a planar surface. For each bottleβbrush polyelectrolyte, flexible charged side chains are anchored to one neutral main chain. The effects of the counterion valence and the grafting density on the de
A Monte Car10 study is presented to discuss the influence of the side-chain topology on the enhancement of the persistence length of a molecular bottle-brush in a dilute athermal solution due to the excluded volume interactions between the side chains. The structures investigated consisted of freely