Molecular association of CH3OD vapor
β Scribed by Richard G. Inskeep; Frank E. Dickson; Helen McKuskie Olson
- Publisher
- Elsevier Science
- Year
- 1961
- Tongue
- English
- Weight
- 324 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0022-2852
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π SIMILAR VOLUMES
K = 1 + 0 transitions in CHsOD for / = 1, 2, 3 and 4 E,-type states were measured using a beam maser spectrometer with 6 kHz linewidth (fwhm). Analysis of J = 1 and / = 2 spectra provided a deuterium quadrupole coupling strength along the O-D bond di?ection of eqzzQ = 303 i 12 kHz.
Using an extended version of the internal axis method previously introduced to analyze the rotational spectrum of methanol to microwave accuracy, we have reanalyzed new and existing data for \(\mathrm{CH}_{3} \mathrm{OD}\) in the three lowest torsional levels \(\left(v_{t}=0,1,2\right)\). As in the
The high resolution Fourier transform far infrared spectrum of the torsion rotation band of CH 3 OD has been recorded in the range 20-350 cm 01 at a resolution of 0.002 cm 01 . The spectrum shows splitting of the lines due to strong torsional, rotational, and vibrational interactions in the molecule