Molecular arrangements in sphingolipids. Crystal structure of N-tetracosanoylphytosphingosine
✍ Scribed by Dahlén, B. ;Pascher, I.
- Book ID
- 117857942
- Publisher
- International Union of Crystallography
- Year
- 1972
- Weight
- 879 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0567-7408
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The conformation and molecular packing of a ceramide, N-(2D,3n-dihydroxyoctadecanoyl)-phytosphingosine, has been determined by single crystal analysis (R = 0.095). The lipid crystallizes in the space group P21 with unit cell dimensions a = 7.23, b = 7.39, c = 35.80 A. and fl = 92.9 °. The two molecu
Chiral compounds, N-methyl-, N-ethyl-, and N-n-propylcholamides, form crystalline inclusion compounds with water or small organic substances. The compounds were analyzed by X-ray diffraction methods. It was found that the crystals have bilayered structures accumulated by chiral molecular sheets. The