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Molecular and crystal structure of the bola-amphiphile N-[8-(d-gluconamido)octyl]-d-gluconamide

✍ Scribed by Anke Müller-Fahrnow; Wolfram Saenger; Detlef Fritsch; Peter Schnieder; Jürgen-Hinrich Fuhrhop

Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
619 KB
Volume
242
Category
Article
ISSN
0008-6215

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✦ Synopsis

The crystal structure of the title compound [5; space group P2,; a = 8.375(5). b = 51.52(2), c = 5.647(3) A; p = 89.64( 4)"] was determined by X-ray diffraction methods and refined to R = 0.107. There are two molecules in the asymmetric unit, which adopt nearly identical conformations.

Each molecule has two parts that differ only in the torsion angle N-C-7-C-8-C-9, which can be synclinal (-64") or anti (168"). The molecules are arranged in sheets and the packing is stabilised by strong intra-and inter-molecular hydrogen bonds, some of which form a homodromic arrangement.

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