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Molecular and crystal structure of p-dimethylaminophenyl-p,p-dimethylphosphine selenide p-Me2NC6H4P(Se)Me2

โœ Scribed by V. V. Tkachev; L. O. Atovmyan; A. A. Shvets; O. A. Osipov


Publisher
SP MAIK Nauka/Interperiodica
Year
1984
Tongue
English
Weight
241 KB
Volume
25
Category
Article
ISSN
0022-4766

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The reaction of one equivalent of In with a molten flux of (Ph 4 P) 2 Se 5 and P 2 Se 5 (1 : 2), at 250 ยฐC gave the (Ph 4 P)[In(P 2 Se 6 )] (I). Stoichiometric elemental synthesis at 750 ยฐC produced the Cs 5 In(P 2 Se 6 ) 2 (II). The thin, yellow crystals of (I), and the irregular, dark orange cryst