Molecular and crystal structure of Cu(HCOO)(OH)
โ Scribed by Hatsue Tamura; Kazuhide Ogawa; Wasuke Mori; Michihiko Kishita
- Book ID
- 104138050
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 262 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0020-1693
No coin nor oath required. For personal study only.
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Unpolarized Raman spectra of policrystalline samples of calcium (II)+copper (II) formate [CaCu(HCOO) 4 ] and dicalcium (II)+copper (II) formate [Ca 2 Cu(HCOO) 6 ] were recorded and analyzed in the temperature range from 30 to 300 K. The observed modes at 300 K were assigned on the basis of formate g
Ba 2 Cu(HCOO) 6 grown at room temperature crystallizes in space group P2 On heating, the following changes are observed: (1) a reversible, hysteretic, 5rstorder phase transition at about 40}903C; (2) partial decomposition at 1903C; and (3) an irreversible change at 2303C related to decomposition. W
Polarized Raman spectra of single crystals of barium copper formate [Ba 2 Cu(HCOO) 6 ] at room temperature were recorded and analysed. The spectra were obtained for geometries allowing the observation of A(TO) and B (TO Y LO) species. The assignment of the fundamental modes was performed on the basi