## Abstract Supramolecular crosslinking was studied in reversible loose‐fit rotaxanation between a size‐mismatched ring and a dumbbell‐shaped chain attached to bulky terminals through slipping of the crosslinked rings onto the chain using a combination of β‐cyclodextrin (β‐CD) and poly(ethylene gly
✦ LIBER ✦
Modulation of reversible self-assembling of dumbbell-shaped poly(ethylene glycol)s and β-cyclodextrins: precipitation and heat-induced supramolecular crosslinking
✍ Scribed by Kobayashi, Yuichiro; Katoono, Ryo; Yamaguchi, Masayuki; Yui, Nobuhiko
- Book ID
- 119980331
- Publisher
- Nature Publishing Group
- Year
- 2011
- Tongue
- English
- Weight
- 553 KB
- Volume
- 43
- Category
- Article
- ISSN
- 0032-3896
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## Abstract A novel supramolecular network has been prepared based on the formation of inclusion complexes between __γ__‐cyclodextrin and poly(ethylene glycol), in which the PEG chains are interlocked by __γ__‐CD rings. This PEG/__γ__‐CD network exhibits good shape memory behavior because of the cr