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Modulation of Magnetic Properties at Room Temperature: Coordination-Induced Valence Tautomerism in a Cobalt Dioxolene Complex

✍ Scribed by Witt, Alexander; Heinemann, Frank W.; Sproules, Stephen; Khusniyarov, Marat M.


Book ID
126947434
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
946 KB
Volume
20
Category
Article
ISSN
0947-6539

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An electronic switch at the molecular level has been realized by using a class of ionic compounds of the formula [Co(L)(diox)]Y (L tetraazamacrocyclic ligand, Y mononegative anion). Such compounds undergo temperature-and pressure-induced intramolecular one-electron transfer equilibria. The transitio