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Modulation effects in the electron spin echo of trans bis-(2,2,5,5-tetramethyl-3-imidazoline-3-oxide-1-oxyl-4-il) ethylene biradicals

✍ Scribed by S.A. Dikanov; A.V. Astashkin; Yu.D. Tsvetkov


Publisher
Elsevier Science
Year
1984
Tongue
English
Weight
465 KB
Volume
105
Category
Article
ISSN
0009-2614

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✦ Synopsis


Electron spin echo modulation effects have been invcstlgated in trans bls(2,2~,5-tetramcthyl-3-unidazoline-3~~idc-l-oxyl4-il) ethylene biradicals involvin_e 14N OI "N nuclei in different positions_ The modulation frequencies are shown to be the nitrogen nuclear tranntion frequencies in radical fra,wents at rns = 0 of a triplet electronic spir. Quadrupole sphttin_g parameters for these nitrogen nuclei have been determined.