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Modular Synthesis of ChiraClick Ligands: A Library of P-Chirogenic Phosphines.

✍ Scribed by Franck Dolhem; Magnus J. Johansson; Thomas Antonsson; Nina Kann


Publisher
John Wiley and Sons
Year
2007
Weight
17 KB
Volume
38
Category
Article
ISSN
0931-7597

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Modular P-Chirogenic Aminophosphane-Phos
✍ Christophe Darcel; Dominique Moulin; Jean-Christophe Henry; Michaël Lagrelette; 📂 Article 📅 2007 🏛 John Wiley and Sons 🌐 English ⚖ 258 KB

## Abstract An original series of P‐chirogenic aminophosphane‐phosphinite (AMPP) ligands has been synthesized from (+)‐ or(–)‐ephedrine in 23 to 61 % overall yields by a versatile three‐step methodology. The AMPP ligands, bearing either one or two P‐chirogenic centers, were used in the form of rhod