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Modular Synthesis of 1,2-Diamine Derivatives by Palladium-Catalyzed Aerobic Oxidative Cyclization of Allylic Sulfamides

✍ Scribed by Richard I. McDonald; Shannon S. Stahl


Publisher
John Wiley and Sons
Year
2010
Tongue
English
Weight
332 KB
Volume
122
Category
Article
ISSN
0044-8249

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Palladium on Carbon-Catalyzed Synthesis
✍ Shigeki Mori; Masato Takubo; Takayoshi Yanase; Tomohiro Maegawa; Yasunari Monguc 📂 Article 📅 2010 🏛 John Wiley and Sons 🌐 English ⚖ 158 KB 👁 1 views

## Abstract A palladium on carbon (Pd/C)‐catalyzed synthetic method for the preparation of benzil derivatives from 1,2‐diarylalkynes has been established using dimethyl sulfoxide (DMSO) and molecular oxygen as dual oxidants. Regardless of the electrical nature of the functional groups on the aromat