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Modular Bis(oxazoline) Ligands for Palladium-Catalyzed Allylic Alkylation: Unprecedented Conformational Behavior of a Bis(oxazoline) Palladium η3-1,3-Diphenylallyl Complex.

✍ Scribed by Miquel Angel Pericas; Cristina Puigjaner; Antoni Riera; Anton Vidal-Ferran; Montserrat Gomez; Francisco Jimenez; Guillermo Muller; Merce Rocamora


Book ID
101939792
Publisher
John Wiley and Sons
Year
2003
Weight
146 KB
Volume
34
Category
Article
ISSN
0931-7597

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Modular Bis(oxazoline) Ligands for Palla
✍ Miquel Angel Pericàs; Cristina Puigjaner; Antoni Riera; Anton Vidal-Ferran; Mont 📂 Article 📅 2002 🏛 John Wiley and Sons 🌐 English ⚖ 286 KB 👁 2 views

New families of enantiopure bis(oxazolines) with 4,5-trans (5 a-g) or 4,5-cis (6 c) stereochemistry at the individual rings have been prepared in high yield. Their eta(3)-allyl palladium complexes (8 a-g, 9 c and 10) have been used as catalytic precursors in allylic alkylation reactions with excelle