Modular Bis(oxazoline) Ligands for Palla
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Miquel Angel Pericàs; Cristina Puigjaner; Antoni Riera; Anton Vidal-Ferran; Mont
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Article
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2002
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John Wiley and Sons
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English
⚖ 286 KB
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New families of enantiopure bis(oxazolines) with 4,5-trans (5 a-g) or 4,5-cis (6 c) stereochemistry at the individual rings have been prepared in high yield. Their eta(3)-allyl palladium complexes (8 a-g, 9 c and 10) have been used as catalytic precursors in allylic alkylation reactions with excelle