✦ LIBER ✦
Modifiziertes PPP-Verfahren zur Berechnung schwacher molekülkomplexe. Einfluss der struktur auf die UV-Spektren von TCNE-Komplexen phenylsubstituierter Äthylene
✍ Scribed by Joachim Sauer; Heinz Mustroph
- Book ID
- 102979641
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 982 KB
- Volume
- 8
- Category
- Article
- ISSN
- 0001-8716
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✦ Synopsis
The CT-spectra of complexes of phenyl-substituted ethylenes, with TCNE as acceptor in various arrangements, are calculated. Conclusions about the structure of such weak complexes in solution may be drawn from a comparison with experimental electronic spectra. Within the framework of this static structural model the two observed CT-bands are explained by absorption from preferred arrangements; the acceptor is arranged about the double bond (first CT-band) * TCNE -Tetracyanolthylen.