Modified texture and high temperature transport properties of doubly substituted BaxAgyCa2.8Co4O9 thermoelectric oxide
β Scribed by F.P. Zhang; Q.M. Lu; J.X. Zhang
- Publisher
- Elsevier Science
- Year
- 2009
- Tongue
- English
- Weight
- 485 KB
- Volume
- 404
- Category
- Article
- ISSN
- 0921-4526
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π SIMILAR VOLUMES
A new complex oxide with the cation ratio Ca:Co: Ga=2:0.8:1.2 has been synthesized in air at 1150 o C. The cobalt atoms adopt oxidation states 2+ and 3+ in equal amounts giving an oxygen content corresponding to the composition Ca 2 Co 0.8 Ga 1.2 O 4.8 . It crystallizes in F-centered cubic structure
Ca 3 Γ x Er x Co 4 O 9 + d (x ΒΌ 0, 0.05, 0.15, 0.3 and 0.5) samples were prepared using a sol-gel method followed by hot-pressing sintering technique. Powder X-ray diffraction analysis showed the single-phases of Ca 3 Γ x Er x Co 4 O 9 + d were obtained up to x ΒΌ 0.3 and the crystallinity of the sam