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Modified Morse Potential for Diatomic Molecules

✍ Scribed by A.R. Lee; T.M. Kalotas; N.A. Adams

Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
140 KB
Volume
191
Category
Article
ISSN
0022-2852

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✦ Synopsis

We present a diatomic potential which closely resembles the standard Morse function but incorporates additional flexibility for fitting experimental vibrational energy-gap data. This flexibility is accommodated by introducing a continuously variable radially dependent change in the exponent of the Morse function, which in practice is adequately realized via a relatively small number of constant parameters. As an illustration, the method is applied to calculate the quantum vibrational levels of the X1Sigma+g ground electronic state of the N2 molecule. Copyright 1998 Academic Press.

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