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Modified BINAPO Ligands for Rh-Catalyzed Enantioselective Hydrogenation of Acetamidoacrylic Acids and Esters.

✍ Scribed by Rongwei Guo; Terry T.-L. Au-Yeung; Jing Wu; Michael C. K. Choi; Albert S. C. Chan

Publisher
John Wiley and Sons
Year
2003
Weight
122 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract A small library of chiral BINOL‐derived monodentate phosphites containing either a carboxylic acid (‐COOH, **A1**–**A3**) or a tertiary amine (‐NMe~2~, **B1**–**B4**) was synthesized. The ligand combinations were screened in the enantioselective rhodium‐catalyzed hydrogenation of methyl