Using the Rouse-Zimm model of the macromolecule, the stress constitutive equation of dilute polymer solutions is derived in the form of a functional of temperature and deformation histories. The non-equilibrium thermodynamics of the system is also considered by relating excess freeenergy, entropy a
β¦ LIBER β¦
Modified bead spring theory of dilute polymer solutions. III. Inclusion of multiple relaxation times
β Scribed by A. E. Everage Jr.; R. J. Gordon
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 713 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0021-8995
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## Abstract A constitutive equation which has proven quite successful in describing the nonlinear viscoelastic behavior of dilute polymer solutions is extended to the case of molten polymers. The techniques utilized and similar to those discussed by Ferry in a similar adaptation of the RouseβZimm T
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