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Modification of the acid-base properties of hydroxycarbonyl complexes of iridium(III) by substitution of carbon monoxide by a tertiary phosphine ligand

✍ Scribed by Antony J. Deeming; Graeme P. Proud


Publisher
Elsevier Science
Year
1986
Tongue
English
Weight
427 KB
Volume
301
Category
Article
ISSN
0022-328X

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## Abstract The deprotonation under basic conditions of the keto‐phosphane ligand in complexes {Ru(Cp)[Ξ·^1^‐__P__‐Ph~2~PCH~2~C(=O)__t__Bu](PPh~3~)(L)}[PF~6~] (L = CO or PMe~3~) that arise from the addition of L to {Ru(Cp)[Ξ·^2^‐__P__,__O__‐Ph~2~PCH~2~C(__t__Bu)=O](PPh~3~)}[PF~6~] generates {Ru^+^(Cp