Modification of poly(vinyl alcohol) with acid chlorides and crosslinking with difunctional hardeners

✍ Scribed by V. Giménez; A. Mantecón; V. Cádiz

• Publisher: John Wiley and Sons
• Year: 1996
• Tongue: English
• Weight: 703 KB
• Volume: 34
• Category: Article
• ISSN: 0887-624X
• DOI: 10.1002/(sici)1099-0518(19960430)34:6<925::aid-pola1>3.0.co;2-h

✦ Synopsis

The reaction of acid chlorides with poly(viny1 alcohol) (PVA) leads to vinyl alcohol-vinyl ester copolymers. The esterification by Schotten-Baumann enables degrees of modification to be reached which depend on the chemical structure of the pendant unit introduced. High degrees of modification were obtained in the reaction with water-stable acid chlorides such as benzoyl or cinnamoyl chloride. The copolymers obtained were characterized by spectroscopic techniques, elemental analysis, thermal methods, and viscosity determinations. Since in all cases they were only partially modified, the remaining hydroxyl groups were reacted with difunctional hardeners, Epiclon B-4400, hexamethylene diisocyanate, and tolylene 2,4-diisocyanate, to obtain tridimensional networks. Vinyl alcohol-vinyl benzoate copolymers with different degrees of modification were crosslinked to study how the percentage of remaining hydroxylic groups affects the crosslinking process. The exotherm maximum of the curing process was lower when diisocyanates were used as hardeners and the degree of crosslinking was higher when hexamethylene diisocyanate was used according to the observed increase in T, values. Whereas the TGA curves of linear polymers only showed one degradation, in crosslinked polymers two degradation steps were detected, suggesting several degradation mechanisms.