Modification of photochemical reactivity by zeolites: Cation enhanced α-cleavage of aryl alkyl ketones included in faujasites

Modification of photochemical reactivity

Modification of photochemical reactivity by zeolites: Role of cations in controlling the behavior of radicals generated within faujasites

✍ V. Ramamurthy; D.R. Corbin; D.F. Eaton; N.J. Turro 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 258 KB

a-Alkyldibenzylketones included in cation exchanged faujasite type zeolites show photobehavior different from that in isotropic organic solvents. Rearrangement and disproportionation which do not contribute in solution are the major processes within the cavities of faujasites. Cation size plays a m