2-alkylbenzothiazoles undergo Claisen-type self-condensation reaction simply on treatment with Grignard reagents. In theprecedingpaper we have described a novel ring opening reaction of benzothiazoles with allylic Grignard reagents.' The reaction was specific of allylic Grignards, as we found that b
โฆ LIBER โฆ
Modes of reaction of grignard reagents with carbamates
โ Scribed by Yitzhak Wiesel; Raul Suchi; Michael Michman; Saul Patai
- Publisher
- Elsevier Science
- Year
- 1973
- Tongue
- French
- Weight
- 180 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0040-4039
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โฆ Synopsis
Although the reactions of Grignard reagents with amrdes and esters are well documented', very little has been published on their reactions with carbamates R1R2NCOOR3 (I) which contain both ester and amide functions. Zerewitinoff2 reported the determination of active hydrogen of urethan (I, R1 = R2 = H, R3 = Et) by the use of RMgx. Hoch and Klein' reported the reaction of N-cyclohexylideneurethan with aryl-
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