๐”– Bobbio Scriptorium
โœฆ   LIBER   โœฆ

Modern Organocopper Chemistry || Mechanisms of Copper-mediated Addition and Substitution Reactions

โœ Scribed by Krause, Norbert

Publisher
Wiley-VCH Verlag GmbH
Year
2002
Tongue
German
Weight
399 KB
Category
Article
ISBN-13
9783527600083

No coin nor oath required. For personal study only.

๐Ÿ“œ SIMILAR VOLUMES

Kinetics and mechanism of the reaction o
Kinetics and mechanism of the reaction of substituted benzyl bromides with copper in dimethylformamide
โœ Anatoly M. Egorov; Svetlana A. Matyukhova; Alexander V. Anisimov ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 182 KB ๐Ÿ‘ 1 views

The reaction of copper metal with various substituted benzyl bromides in dimethylformamide has been studied and the kinetic and thermodynamic parameters of the reaction have been obtained. Hammett plots of log(k/k โ€ข ) vs the substituent constant ฯƒ gave good correlations (ฯ = 0.24, S ฯ = 0.03, r = 0.