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The (3000) Ge-H stretching overtone band of germane, GeH, (conventionally described as 3u,) has been observed near 6130 cm-' by Fourier transform infrared spectroscopy with a resolution of 0.01 cm-i. The rotational structure shows no sign of the tetrahedral splitting patterns normally characteristic
The constants of thermolysis rate of C,H,~(CH,),~O~(CH,),-C6HS ethers were measured in conditions close to those of coal liquefaction (hydrogen pressure of 8.5 MPa; temperature up to 410°C) but minimizing secondary conversions (i.e. in ten-fold excess of tetralin). The ethers form the following reac
A weakly bound complex of NH 3 and F 2 has been detected as a pre-reactive intermediate in mixtures of the component gases and characterised by means of its ground-state rotational spectrum. Chemical reaction of NH 3 and F 2 was precluded by using a fast-mixing nozzle in a Fourier-transform microwav