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Models for the Initial Stages of Oxidative Addition. Synthesis, Characterization, and Mechanistic Investigation of η 1 -I 2 Organometallic “Pincer” Complexes of Platinum. X-ray Crystal Structures of [PtI(C 6 H 3 {CH 2 NMe 2 } 2 -2,6)(η 1 -I 2 )] and exo-meso -[Pt(η 1 -I 3 )(η 1 -I 2 )(C 6 H 3 {CH 2 N( t -Bu)Me} 2 -2,6)]

✍ Scribed by Gossage, Robert A.; Ryabov, Alexander D.; Spek, Anthony L.; Stufkens, Derk J.; van Beek, Johannus A. M.; van Eldik, Rudi; van Koten, Gerard

Book ID
121210932
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
171 KB
Volume
121
Category
Article
ISSN
0002-7863

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The chemistry of cobalt acetate. X. The
The chemistry of cobalt acetate. X. The preparations of the mixed ligand cobalt oligomers, [Co3O(C6H5N2O)3(CH3CO2)3][PF6].CH3CN (I), [Co4(μ2-OH)2(η1:η1:μ2-CH3COO)2(CH3CO2)2 (η1:η1:μ2-C11H8NO)2(η1:η1:η1:η1:μ2-C11H8N3O)2][PF6]2.CH3OH.3H2O (II) and [Co3O(CH3CO2)5(C7H6NO2)(py)3][PF6] (III) and the crystal structures of (I) and (II). Comparisons with homoleptic cobalt acetate dimers and trimers
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