Models for glycoside hydrolysis. Synthesis and hydrolytic studies of the anomers of a conformationally rigid acetal
β Scribed by Van Eikeren, Paul
- Book ID
- 127079955
- Publisher
- American Chemical Society
- Year
- 1980
- Tongue
- English
- Weight
- 699 KB
- Volume
- 45
- Category
- Article
- ISSN
- 0022-3263
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π SIMILAR VOLUMES
Solid superacids, perfluorinated resin-sulfonic acid catalysts, were utilized to hydrolyze glycosidic bonds in di-and polysaccharides. In batch experiments cellobiose and starch, at concentrations of 100 g/1 were completely hydrolyzed at 95 ~ C. The reaction catalyzed by solid superacids did not see
Kinetic results on the glucoamylase-catalysed hydrolysis of maltose and maltotriose, and glucose polymerization into maltose and isomaltose up to 450 g/L total sugar concentration are presented. Whereas the enzyme has a faster hydrolytic and synthetic activity on ~(1'4) than on a-(I -6) linkages, at