Models for Bimetallic Catalysts: Multiple Oxidation States in Pt3Re Cluster Cations

✍ Scribed by Leijun Hao; Dr. Jianliang Xiao; Dr. Jagadese J. Vittal; Prof. Richard J. Puddephatt

• Publisher: John Wiley and Sons
• Year: 1995
• Tongue: English
• Weight: 360 KB
• Volume: 34
• Category: Article
• ISSN: 0044-8249
• DOI: 10.1002/anie.199503461

✦ Synopsis

The higher stability of the picket-fence porphyrin derivatives relative to those obtained with other porphyrins (H,TPP, H,TPFPP, H,TMPf2. 3 , 'I) indicates that the 0x0 group of the Mn=O moiety of 2 probably lies in the hydrophobic cavity formed by the four pivalamide pickets of this porphyrin.