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Modelling tyrosinase monooxygenase activity. Activation of dioxygen by dicopper(I) complexes and characterisation of dicopper(II) complexes

✍ Scribed by Rajeev Gupta; Debalina Ghosh; Rabindranath Mukherjee

Book ID
110643323
Publisher
Indian Academy of Sciences,Royal Society of Chemistry
Year
2000
Tongue
English
Weight
89 KB
Volume
112
Category
Article
ISSN
0253-4134

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Theoretical Studies on ortho-Oxidation of Phenols with Dioxygen Mediated by Dicopper Complex: Hints for a Catalyst with the Phenolase Activity of Tyrosinase
✍ Hiroshi Naka; Yoshinori Kondo; Shinya Usui; Yuichi Hashimoto; Masanobu Uchiyama πŸ“‚ Article πŸ“… 2007 πŸ› John Wiley and Sons 🌐 English βš– 315 KB πŸ‘ 1 views

## Abstract Theoretical studies on the chemo‐ and regioselective __ortho__‐oxidation reaction of phenols mediated by a biomimetic (__μ–η__^2^:__Ξ·__^2^peroxo)dicopper(II) complex were performed using unrestricted hybrid density functional theory (UB3LYP) calculations, with the aim of providing a gui